We can load CSS asynchronously like this:
<link rel="stylesheet" href="style.css" media="print" onload="this.media='all'; this.onload=null;">
When should I use it?
Keep in mind that CSS is render-blocking. Performance-wise this is a problem as the browser is downloading the CSS, it stops painting the page.
Therefore any CSS that is not critical to the above-the-fold content is a good candidate to be loaded async. Also, keep in mind that the 14kb-ish is the size of a single roundtrip HTTP request, so it would be great to keep the critical CSS under this size.
How does it work?
You can read more about it in this initial article written by Scott Jehl.
Why can I use the link preload attribute to load CSS async?
Yes, you can and it works. Just that it seems that the
media="print" approach will give better results. As Scott Jehl explains:
"More importantly though, preload fetches files very early, at the highest priority, potentially deprioritizing other important downloads, and that may be higher priority than you actually need for non-critical CSS."